Yes, it should work and still give you a discount. I can use my card in a store near me that is in the Central division instead of Cincinnati division and I get 10% off Kroger brand there too. It's weird going to that store because they have items we can't get in our order guide so i'm jealous lol.
Yes, you should be able to receive the Fuel Discount at all locations. "Our Brands" discount wasn't guaranteed, because some Div's before didn't have the same employee discounts, which has now changed. I personally think they should do more employee discount events, give an extra 10% off "Our Brands" (20% or more) random days/weekends. In reality anything random or not "normal" is seen as a perk and not already expected....... give $5.00 off an order, give 500 fuel points ....something, anything different to keep associates thinking they are receiving a "perk". Hell, change the discontinued item process, if the items are going to get market down ....why not reset the shelf and give associates a shelf on the back dock for items "Associates Priced" if the items do not sell after that....discount rack? In reality there are many different things we could do to give more perks to associates that really cost nothing.
I have found that using my Kroger loyalty card for fuel points in different divisions, limits me to a max of ten cents off a gallon,
regardless of how many fuel points I have.